Which statements are NOT TRUE about XeO2F2? A. It has a see-saw shape. B. Xe has 5 electron pairs in its valence shell in XeO2F2. C. The O−Xe−O bond angle is close to 180∘. D. The F−Xe−F bond angle is close to 180∘. E. Xe has 16 valence electrons in XeO2F2.
Choose the correct answer from the options given below.
(A)B, C and E only✓ Correct
(B)B and D only
(C)A and D only
(D)B, D and E only
Answer: (A)
Solution
XeO2F2 places four bonding regions (two Xe=O, two Xe--F) and one lone pair about xenon, a trigonal-bipyramidal arrangement that gives a see-saw shape, with the lone pair and the two oxygen atoms equatorial and the two fluorine atoms axial. The F--Xe--F angle is therefore close to 180∘, so those two descriptions are correct. The O--Xe--O angle is the equatorial angle of about 105∘, not 180∘; xenon brings eight valence electrons, not sixteen; and counting its σ bonds, π bonds and lone pair gives seven electron pairs, not five. The statements that are not true are that xenon has five electron pairs, that the O--Xe--O angle is near 180∘, and that xenon has sixteen valence electrons.
JEE Main · 2026 · 23 Jan 2026 · Shift 2 · Single correct option