JEE Main · 2024 · 01 Feb 2024 · Shift 2 · p-Block Elements

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Given below are two statements:

Statement (I): SiO₂ and GeO₂ are acidic while SnO and PbO are amphoteric in nature.
Statement (II): Allotropic forms of carbon are due to property of catenation and pπ-dπ bond formation.

In the light of the above statements, choose the most appropriate answer from the options given below:
  1. (A)Both Statement I and Statement II are false
  2. (B)Both Statement I and Statement II are true
  3. (C)Statement I is true but Statement II is false✓ Correct
  4. (D)Statement I is false but Statement II is true

Answer: (C)

Solution

Moving down group 14, oxide character shifts from acidic to amphoteric as metallic character increases: and are acidic, while and are amphoteric — Statement I is true. Carbon's allotropes (diamond, graphite, fullerenes) arise from its ability to catenate and to form - bonds with itself; carbon has no available d-orbitals in its valence shell, so it cannot form - bonds — Statement II, which attributes the allotropy to - bonding, is false.

JEE Main · 2024 · 01 Feb 2024 · Shift 2 · Single correct option

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