The ratio of number of oxygen atoms to bromine atoms in the product Q is ______ ×10−1.
Answer: 15
Solution
Nitration of the ethoxybenzene (HNO3/H2SO4) installs one −NO2 group ortho/para to −OC2H5 (product P), contributing 2 oxygens (from NO2) plus 1 oxygen (from −OC2H5) — 3 oxygens total. Bromination with excess Br2/Fe, directed by the strongly activating ethoxy group, installs 2 bromine atoms in product Q. Ratio of oxygen to bromine atoms =3:2=1.5=15×10−1.