JEE Advanced · 2024 · 26 May 2024 · Paper 1 · Aldehydes Ketones and Carboxylic Acids

WhatsApp Email
Reaction of iso-propylbenzene with followed by the treatment with forms phenol and a by-product P. Reaction of P with 3 equivalents of gives compound Q. Treatment of Q with produces compound R and calcium salt S.
The correct statement(s) regarding P, Q, R and S is(are)
  1. (A)Reaction of P with R in the presence of KOH followed by acidification gives (see structure)
    ✓ Correct
  2. (B)Reaction of R with in the presence of light gives phosgene gas✓ Correct
  3. (C)Q reacts with aqueous NaOH to produce and
  4. (D)S on heating gives P✓ Correct

Answer: (A), (B), (D)

Solution

Cumene (iso-propylbenzene) undergoes cumene hydroperoxide process to give phenol and acetone (P). Acetone reacts with 3 to give chloroform (, R) and calcium acetate (S) via haloform reaction with . (A) Acetone + chloroform with KOH gives chloretone. (B) Chloroform with /light gives phosgene (). (C) is incorrect: Q () does not undergo Cannizzaro reaction. (D) Calcium acetate on heating gives acetone.

JEE Advanced · 2024 · 26 May 2024 · Paper 1 · One or more correct options

More JEE Advanced questions on Aldehydes Ketones and Carboxylic Acids

  1. The sum of total number of carbonyl groups present in the major products X and Y in the following reactions is ____.
    JEE Advanced 2026View solution →
  2. The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match each entry in List-I with the appropriate entry in List-II and choose the correct options.

    List-I
    (P) Stephen reaction
    (Q) Sandmeyer reaction
    (R) Hoffma …
    JEE Advanced 2025View solution →
  3. The correct reaction/reaction sequence that would produce a dicarboxylic acid as the major product is
    JEE Advanced 2025View solution →
  4. Complete reaction of acetaldehyde with excess formaldehyde, upon heating with conc. NaOH solution, gives P and Q. Compound P does not give Tollens' test, whereas Q on acidification gives positive Tollens' test. Treatment of P with excess cyclohexanone in the presence of catalytic …
    JEE Advanced 2024View solution →
  5. The option(s) with correct sequence of reagents for the conversion of to is(are) :
    JEE Advanced 2024View solution →
  6. The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match List-I with List-II and choose the correct option.

    List-I
    (P) Etard reaction
    (Q) Gattermann reaction
    (R) Gattermann-Koch reaction
    (S) Rosenmund reductio …
    JEE Advanced 2023View solution →