JEE Main · 2019 · 11 Jan 2019 · Shift 1 · Hydrocarbons

The major product of the following reactions is:

(A)(see structure)
(B)(see structure)
(C)(see structure)
(D)(see structure)
✓ Correct

Answer: (D)

Solution

With excess bromine water the phenol is brominated at the positions activated by the

- OH

group, and at the carbon already bearing the sulphonic acid group the incoming bromine displaces

- SO X_{3} H

in an ipso substitution. The outcome is the brominated phenol in which bromine occupies the ortho and para positions, including the site vacated by the sulphonic acid group.

JEE Main · 2019 · 11 Jan 2019 · Shift 1 · Single correct option

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