Statement-I: Compound (X), shown below, dissolves in NaHCO3 solution and has two chiral carbon atoms
Statement-II: Compound (Y), shown below, has two carbons with sp3 hybridization, one carbon with sp2 and one carbon with sp hybridization
In the light of the above statements, choose the correct answer from the options given below:XY
(A)Statement I is true but Statement II is false
(B)Statement I is false but Statement II is true
(C)Both Statement I and Statement II are true✓ Correct
(D)Both Statement I and Statement II are false
Answer: (C)
Solution
Compound X carries a carboxylic acid group, acidic enough to react with sodium hydrogen carbonate and dissolve with effervescence. On its cyclopentane ring the carbon bearing the acid group and the neighbouring carbon bearing the aroyl group are each attached to four different groups, so the molecule has two chiral carbon atoms, and the first statement holds. In compound Y, the ethyl group supplies two sp3 carbons, the =CH− carbon of the carbon-carbon double bond is sp2, and the central cumulated carbon of the C=C=O ketene unit is sp hybridised, matching the second statement. Both statements are true.
JEE Main · 2026 · 21 Jan 2026 · Shift 2 · Single correct option