JEE Main · 2024 · 09 Apr 2024 · Shift 2 · d and f Block Elements

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Given below are two statements :

Statement I: The higher oxidation states are more stable down the group among transition elements unlike p-block elements.

Statement II : Copper can not liberate hydrogen from weak acids.

In the light of the above statements, choose the correct answer from the options given below :
  1. (A)Both Statement I and Statement II are false
  2. (B)Statement I is false but Statement II is true
  3. (C)Both Statement I and Statement II are true✓ Correct
  4. (D)Statement I is true but Statement II is false

Answer: (C)

Solution

Statement I: Down a group among transition elements, higher oxidation states become more stable (e.g. for Mo/W is more accessible than for Cr), unlike the p-block trend where higher oxidation states become less stable down the group (inert pair effect). This is correctly stated — Statement I is true.

Statement II: V V, so Cu cannot reduce H to H from a weak (or dilute) acid — Statement II is true.

Both statements are true.

JEE Main · 2024 · 09 Apr 2024 · Shift 2 · Single correct option

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