JEE Advanced · 2018 · 20 May 2018 · Paper 2 · Chapter_pending

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LIST-I contains reactions and LIST-II contains major products.
LIST-ILIST-II
P. (see structure)1. (see structure)
Q. (see structure)2. (see structure)
R. (see structure)3. (see structure)
S. (see structure)4. (see structure)
5. (see structure)

Match each reaction in LIST-I with one or more products in LIST-II and choose the correct option.
Structure P
P
Structure Q
Q
Structure R
R
Structure S
S
Structure 1
1
Structure 2
2
Structure 3
3
Structure 4
4
Structure 5
5
  1. (A)
  2. (B)✓ Correct
  3. (C)
  4. (D)

Answer: (B)

Solution

Analyzing each reaction: (P) t-butyl bromide with water undergoes SN1 to give t-butanol (1) and elimination to give isobutylene (4). (Q) t-butyl bromide with methoxide undergoes E2 to give isobutylene (2). (R) t-butyl bromide with ammonia gives elimination to isobutylene (4). (S) t-butyl alcohol with HBr gives SN1 substitution to t-butyl ether (3). The correct matching is P→1,4; Q→2; R→4; S→3.

JEE Advanced · 2018 · 20 May 2018 · Paper 2 · Single correct option

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