JEE Main · 2005 · 08 May 2005 · Offline · d and f Block Elements

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The value of the 'spin only' magnetic moment for one of the following configurations is 2.84 BM. The correct one is
  1. (A) (in strong ligand filed)✓ Correct
  2. (B) (in weak ligand field)
  3. (C) (in weak as well as in strong fields)
  4. (D) (in strong ligand field)

Answer: (A)

Solution

A spin-only moment of BM points, through , to unpaired electrons, since . A ion in a strong field pairs electrons into the lower set, reaching with two of the four electrons paired and two left unpaired, which gives exactly . Weak-field would keep all four unpaired and always keeps three, so the match is in a strong field.

JEE Main · 2005 · 08 May 2005 · Offline · Single correct option

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