JEE Main · 2019 · 09 Apr 2019 · Shift 1 · Biomolecules

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Which of the following statements is not true about sucrose?
  1. (A)The glycosidic linkage is present between of -glucose and of -fructose✓ Correct
  2. (B)It is a non-reducing sugar
  3. (C)It is also named as invert sugar
  4. (D)On hydrolysis it produces glucose and fructose

Answer: (A)

Solution

In sucrose the link joins the anomeric of -glucose to the anomeric of -fructose, an - glycosidic bond. Because both anomeric carbons are tied up, no free aldehyde or keto group is left, so sucrose is non-reducing, and on hydrolysis it gives glucose and fructose, the mixture known as invert sugar. The claim that the linkage is between of glucose and of fructose is the untrue one, since the fructose carbon involved is , not .

JEE Main · 2019 · 09 Apr 2019 · Shift 1 · Single correct option

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