JEE Main · 2021 · 16 Mar 2021 · Shift 2 · Hydrogen

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Statement I : Sodium hydride can be used as an oxidizing agent.
Statement II : The lone pair of electrons on nitrogen in pyridine makes it basic.
Choose the CORRECT answer from the options given below:
  1. (A)Statement I is false but statement II is true✓ Correct
  2. (B)Both statement I and statement II are true
  3. (C)Statement I is true but statement II is false
  4. (D)Both statement I and statement II are false

Answer: (A)

Solution

In sodium hydride the hydrogen is at the oxidation state and the hydride ion is a powerful electron donor, so sodium hydride acts as a strong reducing agent and a strong base and never as an oxidising agent. In pyridine the nitrogen is hybridised and its lone pair sits in an orbital lying in the ring plane, outside the aromatic sextet, so the pair stays available to a proton and the molecule is basic. Statement I is false and Statement II is true.

JEE Main · 2021 · 16 Mar 2021 · Shift 2 · Single correct option

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