JEE Main · 2022 · 26 Jun 2022 · Shift 1 · General Principles and Processes of Isolation of Metals

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Given below are two statements :

Statement I : According to the Ellingham diagram, any metal oxide with higher is more stable than the one with lower .
Statement II : The metal involved in the formation of oxide placed lower in the Ellingham diagram can reduce the oxide of a metal placed higher in the diagram.
In the light of the above statements, choose the most appropriate answer from the options given below :
  1. (A)Both Statement I and Statement II are correct.
  2. (B)Both Statement I and Statement II are incorrect.
  3. (C)Statement I is correct but Statement II is incorrect.
  4. (D)Statement I is incorrect but Statement II is correct.✓ Correct

Answer: (D)

Solution

Statement I is incorrect: In the Ellingham diagram, a metal oxide with LOWER (more negative) ΔG° is MORE stable, not higher.

Statement II is correct: A metal whose oxide formation line lies lower in the Ellingham diagram (more negative ΔG°) can reduce the oxide of a metal whose line lies higher (less negative ΔG°). This is the thermodynamic basis for metallurgical reduction reactions.

JEE Main · 2022 · 26 Jun 2022 · Shift 1 · Single correct option

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