Write the chemical equations for the reactions of glucose with:
i) acetic anhydride
ii) NH₂OH
Also draw the Fischer projections of D-glucose and L-glucose.
i) acetic anhydride
ii) NH₂OH
Also draw the Fischer projections of D-glucose and L-glucose.
Solution
(i)
(ii) (the oxime).
Fischer projections: write the chain CHO (top) to CHOH (bottom). In \textbf{D-glucose} the –OH groups sit right-left-right-right on C-2→C-5; \textbf{L-glucose} is its full mirror image (every –OH switched side, C-5 –OH now on the left).
(ii) (the oxime).
Fischer projections: write the chain CHO (top) to CHOH (bottom). In \textbf{D-glucose} the –OH groups sit right-left-right-right on C-2→C-5; \textbf{L-glucose} is its full mirror image (every –OH switched side, C-5 –OH now on the left).
CBSE Class 12 Board · 2005 · Foreign · Subjective