Rearrange the following in increasing order of their basic strengths: aniline, p-nitroaniline, p-toluidine.
Answer: p-Nitroaniline < aniline < p-toluidine.
Solution
–NO (−I, −M) withdraws the N lone pair → weakest; –CH (+I) donates → strongest:
CBSE Class 12 Board · 2008 · Foreign · Subjective