Give a chemical test to distinguish between a primary and a secondary amine.
Answer: Carbylamine test: the 1° amine + CHCl₃/alc. KOH gives the foul isocyanide; the 2° amine does not.
Solution
Heat with chloroform and alcoholic KOH:
Only primary amines give the offensive isocyanide smell; secondary amines stay silent.
Only primary amines give the offensive isocyanide smell; secondary amines stay silent.
CBSE Class 12 Board · 2006 · Foreign · Subjective