How may the following conversions be carried out?
i) propene to propan-2-ol
ii) anisole to phenol (write the reaction only)
i) propene to propan-2-ol
ii) anisole to phenol (write the reaction only)
Answer: (i) Acid-catalysed Markovnikov hydration. (ii) C₆H₅OCH₃ + HI → C₆H₅OH + CH₃I.
Solution
(i)
(ii) HI cleaves the ether at the O–CH bond (the O–aryl bond survives):
(ii) HI cleaves the ether at the O–CH bond (the O–aryl bond survives):
CBSE Class 12 Board · 2007 · All India · Subjective