Give the structural formula and name of the product of the following reaction: phenol is treated with excess of aqueous bromine.
Answer: 2,4,6-Tribromophenol — a white precipitate; all three o/p positions brominated.
Solution
The –OH group strongly activates the ring; with bromine water all activated positions substitute at once:
Structure: phenol with Br at positions 2, 4 and 6.
Structure: phenol with Br at positions 2, 4 and 6.
CBSE Class 12 Board · 2002 · All India · Subjective