Of the two halides shown in the figure (3-halocyclohex-1-ene and 1-halocyclohex-1-ene), which is an example of an allylic halide?First halide (allylic)Second halide (vinylic)
Solution
An allylic halide carries the halogen on an sp3 carbon \textit{next to} a C=C double bond. In 3-halocyclohex-1-ene, X is on the saturated carbon adjacent to the ring double bond — \textbf{allylic}. In 1-halocyclohex-1-ene, X is attached directly to the sp2 carbon of the double bond — vinylic, not allylic.