CBSE Class 12 · 2024 · Haloalkanes and HaloarenesMultiple Choice

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Assertion (A): Inversion of configuration is observed in the S2 reaction.
Reason (R): The reaction proceeds with the formation of a carbocation.
  1. (A)Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  2. (B)Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of Assertion (A).
  3. (C)Assertion (A) is true, but Reason (R) is false.✓ Correct
  4. (D)Assertion (A) is false, but Reason (R) is true.

Answer: (C)

Solution

S2 is a one-step, concerted backside attack — the configuration inverts (Walden inversion), so A is true.
No carbocation is involved in S2 (carbocations belong to S1), so R is false.
Correct option: (C).

CBSE Class 12 Board · 2024 · Single correct option

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