Consider the following plots of log of rate constant k (logk) vs T1 for three different reactions. The correct order of activation energies of these reactions is
(A)Ea2>Ea1>Ea3✓ Correct
(B)Ea1>Ea3>Ea2
(C)Ea1>Ea2>Ea3
(D)Ea3>Ea2>Ea1
Answer: (A)
Solution
From the Arrhenius equation logk=logA−2.303RTEa, a plot of logk against 1/T is a straight line of slope −2.303REa, so a steeper downward slope corresponds to a larger activation energy. In the graph the line labelled 2 descends most steeply, the line labelled 1 is of intermediate steepness, and the line labelled 3 is almost flat. The activation energies therefore decrease in the order Ea2>Ea1>Ea3.
JEE Main · 2025 · 04 Apr 2025 · Shift 2 · Single correct option