The technique used for purification of steam volatile water immiscible substance is:
- (A)Fractional distillation
- (B)Fractional distillation under reduced pressure
- (C)Distillation
- (D)Steam distillation✓ Correct
Answer: (D)
Solution
Steam distillation purifies substances that are volatile with steam and immiscible with water, even when they carry non-volatile impurities. When steam is passed through such a mixture, the compound co-distils with the water because the sum of the vapour pressures of water and the compound reaches atmospheric pressure at a temperature below the compound's own boiling point. The condensed vapours separate into two immiscible layers, from which the organic compound is recovered — this is how essential oils, aniline and nitrobenzene are purified.
JEE Main · 2024 · 27 Jan 2024 · Shift 2 · Single correct option