JEE Main · 2024 · 27 Jan 2024 · Shift 2 · Practical and Analytical Chemistry

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The technique used for purification of steam volatile water immiscible substance is:
  1. (A)Fractional distillation
  2. (B)Fractional distillation under reduced pressure
  3. (C)Distillation
  4. (D)Steam distillation✓ Correct

Answer: (D)

Solution

Steam distillation purifies substances that are volatile with steam and immiscible with water, even when they carry non-volatile impurities. When steam is passed through such a mixture, the compound co-distils with the water because the sum of the vapour pressures of water and the compound reaches atmospheric pressure at a temperature below the compound's own boiling point. The condensed vapours separate into two immiscible layers, from which the organic compound is recovered — this is how essential oils, aniline and nitrobenzene are purified.

JEE Main · 2024 · 27 Jan 2024 · Shift 2 · Single correct option

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