JEE Main · 2025 · 28 Jan 2025 · Shift 1 · Equilibrium

WhatsApp Email
Ice and water are placed in a closed container at a pressure of 1 atm and temperature 273.15 K . If pressure of the system is increased 2 times, keeping temperature constant, then identify correct observation from following :
  1. (A)Volume of system increases.
  2. (B)Liquid phase disappears completely.
  3. (C)The amount of ice decreases.
  4. (D)The solid phase (ice) disappears completely.✓ Correct

Answer: (D)

Solution

On the phase diagram of water, the solid–liquid coexistence line has a negative slope because ice is less dense than liquid water, so raising the pressure at constant temperature favours the denser liquid phase. Starting exactly on the ice–water coexistence line at 273.15 K and 1 atm, doubling the pressure to 2 atm at the same temperature moves the system into the liquid-only region of the phase diagram, so all the ice present converts completely to water.

JEE Main · 2025 · 28 Jan 2025 · Shift 1 · Single correct option

More JEE Main questions on Equilibrium

  1. The first and second ionization constants of are and respectively. The concentration of in solution is . (N …
    JEE Main 2026View solution →
  2. Which of the following mixture gives a buffer solution with ?
    Given :
    JEE Main 2026View solution →
  3. Consider the general reaction given below at 400 K

    The values of and are studied under the same condition of temperature but variation in x and y.
    (i) and appropriate units
    (ii) and …
    JEE Main 2026View solution →
  4. For the following gas phase equilibrium reaction at constant temperature,

    If the total pressure is atm and the pressure equilibrium constant () is 9 atm, then the degree of dissociation is given as …
    JEE Main 2026View solution →

  5. and are added to a 1 L flask and it is found that the system attains the above equilibrium at …
    JEE Main 2026View solution →
  6. Consider three metal chlorides and z , where x is water soluble at room temperature, is sparingly soluble in water at room temperature and z is soluble in hot water. and z are respectively
    JEE Main 2026View solution →