JEE Advanced · 2023 · 04 Jun 2023 · Paper 2 · Chemical Thermodynamics

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The entropy versus temperature plot for phases and at 1 bar pressure is given.
and are entropies of the phases at temperatures T and 0 K, respectively.

(see diagram)

The transition temperature for to phase change is 600 K and .
Assume is independent of temperature in the range of 200 to and are heat capacities of and phases, respectively.

The value of enthalpy change, (in ), at 300 K is ____.

Answer: 300

Solution

At the transition temperature (600 K), the two phases are in equilibrium:



The enthalpy change varies with temperature as:


At 300 K:


JEE Advanced · 2023 · 04 Jun 2023 · Paper 2 · Numerical answer

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