For the reaction H₂(g) + I₂(g) ⇌ 2HI(g), the attainment of equilibrium is predicted correctly by: [molar concentration vs time graph options in source]
- (A)[graph - refer to source PDF]
- (B)[graph - correct: H₂ & I₂ decrease, HI increases, all level off at equilibrium]✓ Correct
- (C)[graph - refer to source PDF]
- (D)[graph - refer to source PDF]
Answer: (B)
Solution
Starting from only and , as the forward reaction proceeds and fall while rises; the opposing rates become equal at equilibrium, after which all three concentrations stay constant. Because 2 mol HI form per mol (or ) consumed, the HI curve rises about twice as steeply as the reactant curves fall. Graph (B) shows both reactant curves decreasing and the product curve increasing, all levelling off at constant equilibrium values.
JEE Main · 2025 · 24 Jan 2025 · Shift 2 · Single correct option