JEE Main · 2021 · 18 Mar 2021 · Shift 2 · Solid State

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A hard substance melts at high temperature and is an insulator in both solid and in molten state. This solid is most likely to be a/an:
  1. (A)Ionic solid
  2. (B)Metallic solid
  3. (C)Molecular solid
  4. (D)Covalent solid✓ Correct

Answer: (D)

Solution

Hardness together with a high melting point points to a three-dimensional network of strong bonds, which a molecular solid with its weak intermolecular forces cannot provide. A metallic solid has mobile electrons and conducts as a solid. An ionic solid does insulate as a crystal, but melting frees its ions and the melt conducts. A solid that still insulates after melting therefore holds its electrons in localised bonds between neighbouring atoms, so it is a covalent solid.

JEE Main · 2021 · 18 Mar 2021 · Shift 2 · Single correct option

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