JEE Main · 2015 · 04 Apr 2015 · Offline · Chemical Bonding and Molecular Structure

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The intermolecular interaction that is dependent on the inverse cube of distance between the molecule is:
  1. (A)ion-dipole interaction✓ Correct
  2. (B)London force
  3. (C)hydrogen bond
  4. (D)ion-ion interaction

Answer: (A)

Solution

Rank these interactions by how steeply they weaken with distance. An ion sets up a field that falls as , and a dipole placed in it responds to how fast that field changes, so differentiating brings in another factor of and the ion-dipole interaction scales as . For comparison the ion-ion interaction fades only as , while London forces die away far faster, around . The dependence is the one belonging to the ion-dipole interaction.

JEE Main · 2015 · 04 Apr 2015 · Offline · Single correct option

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