The intermolecular interaction that is dependent on the inverse cube of distance between the molecule is:
- (A)ion-dipole interaction✓ Correct
- (B)London force
- (C)hydrogen bond
- (D)ion-ion interaction
Answer: (A)
Solution
Rank these interactions by how steeply they weaken with distance. An ion sets up a field that falls as , and a dipole placed in it responds to how fast that field changes, so differentiating brings in another factor of and the ion-dipole interaction scales as . For comparison the ion-ion interaction fades only as , while London forces die away far faster, around . The dependence is the one belonging to the ion-dipole interaction.
JEE Main · 2015 · 04 Apr 2015 · Offline · Single correct option