Some energy levels of a molecule are shown in the figure. The ratio of the wavelengths r=λ1/λ2, is given by:
(A)r=43
(B)r=31✓ Correct
(C)r=34
(D)r=32
Answer: (B)
Solution
Since E=λhc, each transition's wavelength is inversely proportional to its energy gap, i.e. λ∝ΔE1. Reading the level diagram, λ1 is the jump from −E down to −2E, an energy gap of ΔE1=E, while λ2 is the jump from −E down to −34E, a gap of ΔE2=3E. Hence r=λ2λ1=ΔE1ΔE2=EE/3=31.
JEE Main · 2017 · 02 Apr 2017 · Offline · Single correct option