JEE Main · 2021 · 31 Aug 2021 · Shift 2 · Solid State

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The empirical formula for a compound with a cubic close packed arrangement of anions and with cations occupying all the octahedral sites is . The value of x is ______.

Answer: 1

Solution

In a cubic close-packed array the anions B give per unit cell, and the number of octahedral voids equals the number of packing atoms, so there are octahedral sites. Filling all octahedral sites with cations A places A per cell. The ratio A : B is , so the empirical formula is and .

JEE Main · 2021 · 31 Aug 2021 · Shift 2 · Integer answer

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