JEE Main · 2022 · 29 Jul 2022 · Shift 1 · Chemical Bonding and Molecular Structure

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Number of lone pairs of electrons in the central atom of and , respectively, are :
  1. (A)0, 1, 2 and 2
  2. (B)2, 1, 2 and 0✓ Correct
  3. (C)1, 2, 2 and 0
  4. (D)2, 2, 2 and 0

Answer: (B)

Solution

Lone pairs on each central atom: S has 2 bond pairs + 2 lone pairs (bent) => 2; central O has 2 bond pairs + 1 lone pair (bent) => 1; Cl has 3 bond pairs + 2 lone pairs (T-shaped, ) => 2; S has 6 bond pairs + 0 lone pairs (octahedral) => 0. Hence 2, 1, 2 and 0.
Structure SCl₂
SCl₂
Structure O₃
O₃
Structure ClF₃
ClF₃
Structure SF₆
SF₆

JEE Main · 2022 · 29 Jul 2022 · Shift 1 · Single correct option

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