Write chemical equations for the following reactions:
(i) propanone is treated with dilute Ba(OH)₂
(ii) acetophenone is treated with Zn(Hg)/conc. HCl
(iii) benzoyl chloride is hydrogenated in the presence of Pd/BaSO₄
(i) propanone is treated with dilute Ba(OH)₂
(ii) acetophenone is treated with Zn(Hg)/conc. HCl
(iii) benzoyl chloride is hydrogenated in the presence of Pd/BaSO₄
Answer: (i) Aldol: 2CH₃COCH₃ → 4-hydroxy-4-methylpentan-2-one. (ii) Clemmensen → ethylbenzene. (iii) Rosenmund → benzaldehyde.
Solution
(i)
(4-hydroxy-4-methylpentan-2-one — diacetone alcohol).
(ii)
(iii)
(4-hydroxy-4-methylpentan-2-one — diacetone alcohol).
(ii)
(iii)
CBSE Class 12 Board · 2019 · Subjective