Complete the reaction statements shown in the figure by giving the missing starting material, reagent or product (parts b and c as printed; part a is incomplete in the source).(b)(c)
Solution
Each line of the figure fixes two of {substrate, reagent, product}; supply the third: • H2/Pd–BaSO4 on an acid chloride → the aldehyde (Rosenmund); • SnCl2/HCl then H3O+ on a nitrile → the aldehyde (Stephen); • CrO2Cl2 on toluene → benzaldehyde (Etard). Match the displayed members to one of these patterns and write the missing entry.