Write reactions with conditions for the following conversions:
i) methyl bromide to acetic acid
ii) benzene to toluene
i) methyl bromide to acetic acid
ii) benzene to toluene
Answer: (i) CH₃Br + KCN → CH₃CN, then hydrolyse (H₂O/H⁺, Δ) → CH₃COOH. (ii) Friedel–Crafts: C₆H₆ + CH₃Cl/anhyd. AlCl₃ → C₆H₅CH₃.
Solution
(i)
(nitrile route adds one carbon).
(ii)
(nitrile route adds one carbon).
(ii)
CBSE Class 12 Board · 2001 · Foreign · Subjective