Draw the energy band diagram for an n-type and a p-type semiconductor at T>0K.
Solution
For an n-type semiconductor at T>0K, pentavalent donors create a donor level just below the conduction band; at finite temperature these electrons are excited into the conduction band. For a p-type semiconductor, trivalent acceptors create an acceptor level just above the valence band; valence electrons move up into it, leaving holes in the valence band. n-type: donor level below CB; p-type: acceptor level above VB.